Interaction of copper with fatty acids in Soxhlet extraction and its influence     

Ming Jin  Yanqing Xia  Tianzhu Lei  Junli Qiu  Rui Zhang 《中国地球化学学报》2008,27(2):157-160

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.  相似文献   

GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea   总被引：4，自引：1，他引：3  

Shuanggen Jin  O. F. Luo  P. Park 《Journal of Geodesy》2008,82(12):883-892

The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward electric field, and are not associated with the increase of the O/N₂ ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically coupled upward to generate ionospheric perturbations and oscillations.  相似文献   

GIS支持的城市固体废弃物规划管理信息系统构建     

李劲  王华 《测绘工程》2008,17(1):60-63

研究了基于组件式GIS平台MapX的城市固体废弃物规划管理信息系统的设计与实现;讨论了系统框架与系统功能设计、数据库设计和系统实现的关键技术。以昆明市为例,构建了基于MapX的城市固体废弃物规划管理信息系统。该系统能够实现城市固体废弃物各类数据的采集、表达和输出,提供与城市固体废弃物管理模型无缝集成的接口,可利用地图、文字、表格等多种手段为城市固体废弃物规划管理提供辅助决策。  相似文献   

Study on Recovering the Earth＇s Potential Field Based on GOCE Gradiometry     

Wenbin Shen  Jin Li  Jiancheng Li  Zhengtao Wang  Jinsheng Ning  Dingbo Chao 《地球空间信息科学学报》2008,11(4):273-278

Given the second radial derivative Vrr（P） ｜δs of the Earth＇s gravitational potential V（P） on the surface δS corresponding to the satellite altitude, by using the fictitious compress recovery method, a fictitious regular harmonic field rrVrr（P）^＊ and a fictitious second radial gradient field V：（P） in the domain outside an inner sphere Ki can be determined, which coincides with the real field V（P） in the domain outside the Earth. Vrr^＊（P）could be further expressed as a uniformly convergent expansion series in the domain outside the inner sphere, because rrV（P）^＊ could be expressed as a uniformly convergent spherical harmonic expansion series due to its regularity and harmony in that domain. In another aspect, the fictitious field V^＊（P） defined in the domain outside the inner sphere, which coincides with the real field V（P） in the domain outside the Earth, could be also expressed as a spherical harmonic expansion series. Then, the harmonic coefficients contained in the series expressing V^＊（P） can be determined, and consequently the real field V（P） is recovered. Preliminary simulation calculations show that the second radial gradient field Vrr（P） could be recovered based only on the second radial derivative V（P）｜δs given on the satellite boundary. Concerning the final recovery of the potential field V（P） based only on the boundary value Vrr （P）｜δs, the simulation tests are still in process.  相似文献   

福建戴云山隧道断层性质与稳定性研究     

余成伟  刘星 《云南地质》2008,27(4):509-513

隧道断层（F2）为张性正断层,破坏原岩中较为对称的应力平衡,加之带内岩石破碎,节理裂隙发育,使得断层更加容易坍塌和涌水。建议采用稳定掌子面法和专门支护保证硐室稳定。  相似文献   

辽宁白云三道沟沉积变质改造型金矿     

贾宝剑  刘星  田树海  余成伟  尹飞 《云南地质》2008,27(3)

金矿脉受推覆构造带控制,矿质来自辽河群含金层位,属硅钾蚀变沉积变质改造型金矿。  相似文献   

塔里木盆地孔雀河地区复合含油气系统与有利勘探方向   总被引：1，自引：0，他引：1  

汤达祯  邢卫新  孔凡军  李丹梅  许浩  陶树  高冠峰 《地学前缘》2008,15(2):167-177

运用叠合盆地复合含油气系统的描述方法和评价思路,分析了塔里木盆地孔雀河地区含油气系统复合特征,再现从源岩到圈闭的油气地质演化过程。孔雀河地区含油气系统以断裂复合贯通为主,同时存在不整合面复合贯通,构成寒武系C—(!)—下奥陶统O1(!)—石炭系C(*)—三叠系T(*)—侏罗系J(*)+寒武系—C(!)—下奥陶统O1(*)—志留系S(*)—泥盆系D(*)—侏罗系J(*)改造型复合含油气系统(*)。含油气系统的复合经历3个关键时刻:泥盆纪末是构造格局与古油藏形成期,侏罗纪末和白垩纪末是油气转化、重新分配与油藏调整期。研究区可分为破坏散失区、改造调整区、深埋保存区,其中改造调整区、深埋保存区为有利油气聚集区,处在改造调整区的龙口背斜和维马克—开屏背斜的上古生界和中生界的断背斜圈闭以及下古生界残留古断背斜圈闭是最佳勘探目标。  相似文献   

洞庭湖区土壤实测碳量的分布规律及其对全球变化的响应   总被引：2，自引：1，他引：1  

张建新  邢旭东  鲁江  吕焕哲 《地学前缘》2008,15(5):57

研究区域土壤碳库的分布特征对于全球变化研究、土壤肥力和生态系统的功能评价具有重要意义。在缺乏长期实测资料情况下,国内外多以模型、第二次土壤普查资料或较稀的实测数据进行研究。文中利用洞庭湖区生态地球化学调查实测数据,研究影响该区土壤碳分布的因素认为区域土壤碳量处于全国的中、高级水平;地质地貌条件是影响土壤无机碳量分布的最重要因素;土壤类型对土壤碳量有影响;本区水土流失强度对表层土壤总有机碳量影响不大;经济林、竹林的土地利用方式及防治土壤潜育化有利于土壤的碳储存;从TOC等沉积的时空演化规律说明,本区环境变化是对全球环境变化的响应,为区域土地利用、促进土壤碳固定及全球环境变化研究提供了依据。  相似文献   

应用混合分布研究银川平原地下水埋深对植被的影响   总被引：1，自引：0，他引：1  

孙宪春  金晓媚  万力 《地学前缘》2008,15(5):344

银川平原地处西北干旱地区,自然生态环境在西北地区具有典型性。研究银川平原的生态环境,需要研究植被,它反映多种因素的作用。在影响植被的各种因素中,地下水对植被生长的影响非常重要,但将地下水对植被生长的影响进行定量化分离并不容易。近年来,用混合分布函数处理大量数据的方法受到越来越多的关注,但是混合分布函数的参数求解一直比较困难。文章提出了一种基于混合分布函数和数据直方图之间的关系,用最小二乘法估计参数的新方法;并用这种方法,结合银川平原遥感数据中的归一化植被指数NDVI,对地下水埋深与植被生长的关系进行定量分析,得到地下水埋深对植被影响所服从的正态分布密度函数。  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献